Surface plasmon-enhanced zeolite catalysis under light irradiation and its correlation with molecular polarity of reactants.

نویسندگان

  • Xingguang Zhang
  • Aijun Du
  • Huaiyong Zhu
  • Jianfeng Jia
  • Jun Wang
  • Xuebin Ke
چکیده

Enhanced catalytic performance of zeolites via the plasmonic effect of gold nanoparticles has been discovered to be closely correlated with the molecular polarity of reactants. The intensified polarised electrostatic field of Na(+) in NaY plays a critical role in stretching the C=O bond of aldehydes to improve the reaction rate.

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عنوان ژورنال:
  • Chemical communications

دوره 50 90  شماره 

صفحات  -

تاریخ انتشار 2014